Appendix 3 Miscellaneous Reference Materials


Matrix Analytes Reagents Cavity/Vessel Conditions Detection Ref.

BCR

Sewage amended soil

143

Cd, Cr, Cu, Fe, Mn, Pb, Zn HCl, HNO3

Multimode/

LP closed

1 min at 180 W, 4 min at 480 W,

60 min at 600 W

F-AAS

ETV-AAS

G1
Cd, Cu, Ni, Pb, Zn

1. HNO3

2. HNO3

3. H2O2

4. H2O

Single mode/

open

1. 5 min at 10 W, 10 min at 30 W,

10 min at 60 W

2. 10 min at 60 W

3. 5 min at 60 W

4. 5 min at 50 W

ICP-OES

ICP-MS

G2

BCR

Domestic sewage

sludge 144

Pb HNO3

Multimode/

flow through

5 min at 650 W F-AAS G3
Cu, Mn HNO3, H2O2

Multimode/

flow through

3-5 min at 650W (digestate recirculated through oven) F-AAS G4
Cu, Mn

HNO3,

Isoamyl alcohol

Multimode/

LP closed

3 min at 520 W F-AAS G5
Cd, Cu, Fe, Mn, Pb, Zn

HNO3,

2-ethyl-hexan-1-ol

Multimode/

LP closed

3 min at 520 W F-AAS G6
Cu, Mn, Pb, Zn HNO3

Multimode/

flow through

2 sec at 650 W

(0.5 mL coil, 15.4 mL min-1)

F-AAS G7
Al, As, Ba, Ca, Cd, Cr, Cu, Co, Fe, K, Mg, Mn, Na, Ni, Pb, Sb, Sc, Se, Si, Sn, Ti, Tl, V, Zn, Zr

1. HF, Aqua regia

2. H3BO3

Multimode/

LP closed

1. 8 min at 300 W,

11 min at 600 W

2. 6 min at 300 W

ICP-OES

F-AAS

ETV-AAS

G8

BCR

Sewage sludge 145

Cd, Cr, Cu, Fe, Mn, Pb, Zn HCl, HNO3

Multimode/

LP closed

1 min at 180 W, 4 min at 480 W,

60 min at 600 W

F-AAS

ETV-AAS

G1
Al, As, Ba, Ca, Cd, Cr, Cu, Co, Fe, K, Mg, Mn, Na, Ni, Pb, Sb, Sc, Se, Si, Sn, Ti, Tl, V, Zn, Zr

1. HF, Aqua regia

2. H3BO3

Multimode/

LP closed

1. 8 min at 300 W,

11 min at 600 W

2. 6 min at 300 W

ICP-OES

F-AAS

ETV-AAS

G8

BCR

Industrial sewage sludge

146

Pb HNO3,

Multimode/

flow through

5 min at 650 W F-AAS G3
Cu, Mn HNO3, H2O2

Multimode/

flow through

3-5 min at 650 W (digestate recirculated through oven) F-AAS G4
Cu, Mn, Pb HNO3

Multimode/

LP closed

3 min at 90°C (650 W) ETV-AAS G9
Cu, Mn

HNO3,

Isoamyl alcohol

Multimode/

LP closed

3 min at 520 W F-AAS G5

BCR

Industrial sewage sludge

146 (contd.)

Cu, Mn, Pb, Zn HNO3

Multimode/

flow through

2 sec at 650 W

(0.5 mL coil, 15.4 mL min-1)

F-AAS G7
Cd, Cu, Fe, Mn, Pb, Zn

HNO3,

2-ethyl-hexan-1-ol

Multimode/

LP closed

3 min at 520 W F-AAS G6
Al, As, Ba, Ca, Cd, Cr, Cu, Co, Fe, K, Mg, Mn, Na, Ni, Pb, Sb, Sc, Se, Si, Sn, Ti, Tl, V, Zn, Zr

1. HF, Aqua regia

2. H3BO3

Multimode/

LP closed

1. 8 min at 300 W,

11 min at 600 W

2. 6 min at 300 W

ICP-OES

F-AAS

ETV-AAS

G8

BCR

Brown bread

191

Cd, Cu, Pb HNO3, HClO4, H2SO4

Multimode/

HP closed

10 min at 85 bar DP-ASV G10

EPA

Solid

LCS

Al, As, Be, Cd, Co, Cr, Cu, Mg, Mn, Ni, Pb, Sb, V, Zn HNO3, HCl

Multimode/

MP closed

1 min at 600 W ICP-OES G11

IAEA

Human diet H9

I HNO3, N2H4

Multimode/

HP closed

35 sec at 675 W NAA G12
Cr, Hg, Se

1. HNO3

2. H2O2

Multimode/

HP closed

1. 3 min at 450 W Radiochemical G13
Cd, Cu, Fe, Mn HNO3

Multimode/

LP closed

3 min at 650 W (90°C) ETV-AAS G9
Al HNO3

Multimode/

HP closed

1 min at 150 W, 30 min 0 W,

1 min at 450 W

ICP-OES G14

IAEA

Fresh water W4

Cu, Mn, Pb HNO3

Multimode/

LP closed

3 min at 650 W (90°C) ETV-AAS G9

NIST

Trace elements in glass

613

Pb, U HNO3, HF, HClO4

Multimode/

LP closed

5 min at 90 W, 15 min at 138 W ID G15

NIST

Trace elements in glass

615

Pb, U HNO3, HF, HClO4

Multimode/

LP closed

5 min at 90 W, 15 min at 138 W ID G15

NIST

Portland Cement

636

NA HBF4, HNO3

Multimode/

LP closed

2 min at 600 W NA G16

NIST

Doped Platinum

681

Au, Pd, Pt Aqua regia

Multimode/

LP closed

1-3 hr at 860 KPa ETV-AAS G17

NIST

Alumina

699

Ca, Fe, Mn, Ti H2SO4

Multimode/

MP closed

3 min at 630 W,

5-15 min at 315 W (170°C)

ICP-OES G18

NIST

Wear metals in oil

1085

Ag, Al, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sr, V, Zn HNO3

Multimode/

LP closed

5.5 min to 175°C (574W)

4.5 min at 175-180°C (574W)

ICP-OES G19,G20

NIST

Total diet

1548

Cu, Fe, Mn, Zn

A.

HNO3, H2O2

B.

HNO3, H2O2

C.

HNO3, HClO4


Multimode/

HP closed

Multimode/

HP closed

Multimode/

HP closed


75 sec at 665 W

1 min at 250 W, 2 min at 0 W,

2 min at 250 W, 2 min at 400 W,

2 min at 600 W

150 sec at 950 W, 60 sec at 0 W,

90 sec at 300 W, 90 sec at 500 W,

90 sec at 700 W, 90 sec at 850 W

ETV-AAS G21

NIST

Powdered lead base paint

1579

Pb

A.

HNO3

B.

Same as A


Multimode/

LP closed

HP closed

vessel


7 min at 675 W (90 psi max)

3 min at 270 W

F-AAS G22
Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, P, Pb, S, Sb, Si, Sr, Ti, Zn

1. HNO3

2. HF

3. HBO3

Multimode/

MP closed

1. 15 min at 0 W

2. 8 min at 60 W,

6 min at 90 W,

9 min at 60 W

ICP-OES G23
Al, Ba, Ca, Cu, Mg, Mn, Pb, S, Sb, Ti, Zn

A.

Aqua regia, H2O

B.

HNO3, HF


Multimode/

MP closed

Multimode/

LP closed


20 min at 180 psi

20 min at 190 W, 15 min at 0 W

ICP-OES

NAA

G24

NIST

Trace elements in fuel oil

1634

Ag, Al, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sr, V, Zn HNO3

Multimode/

LP closed

5.5 min to 175°C (574 W)

4.5 min at 175-180°C (574 W)

ICP-OES G19,G20

NIST

Trace elements in water

1643

Bi, Hg

1. HCl, KBr, KBrO3

2. NaBH4, NaOH

Single mode/

flow through

1. 65 sec at 90-120 W

(8.5 mL min-1)

CV-AAS G25, G26

NIST

Urban particulate

1648

Cd, Cu, Fe, Pb

1. HNO3, H2O, H2O2

2. Aqua regia, HF

(optional)

Multimode/

open

1. 15 min at 70 W,

15 min at 150 W,

15 min at 180 W,

1 min at 250 W,

1 min at 600 W

2. 15 min at 70 W,

1 min at 600 W

ETV-AAS G27

NIST

Metals on filter media

2676

Al, As, Ba, Be, Ca, Co, Cr, Fe, Mg, Mn, Ni, P, Pb, S, Ti, V, Zn

A.

HF, Aqua regia

B.

HNO3


Multimode/

LP closed

Multimode/

LP closed


5 min at 200 W,

5 min at 400 W

Same as A

ICP-OES G28

NIST

Multi element mix A

3171

Al HNO3

Multimode/

MP closed

4 min at 200 W, cool,

4 min at 350 W, cool,

8 min at 250 W, cool,

10 min at 400 W (x4)

ETV-AAS G29

NIST

Mixed diet

8431

Ca, Cu, Fe, K, Mg, Mn, P, Zn HNO3, HCl

Multimode/

LP closed

5 min at 300 W, 5 min at 0 W,

5 min at 300 W, 5 min at 450 W,

5 min at 0 W, 5 min at 450 W

ICP-OES G30
Cr, Hg, Se

1. HNO3

2. H2O2

Multimode/

HP closed

1. 3 min at 450 W Radiochemical G13
Al HNO3

Multimode/

HP closed

1 min at 150 W, 30 min at 0 W,

1 min at 450 W

ICP-OES G14

NRCC

Seawater

NASS-2

As, Fe, Se, V HNO3, H2O2

Multimode/

HP closed

- ICP/MS G31

NRCC

Riverine water

SLRS-2

As, Fe, Se, V HNO3, H2O2

Multimode/

HP closed

- ICP/MS G31

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